Resistance of slurry aluminide coatings on pure nickel under different sulphidizing/Hot corrosion conditions at 700 °C

B. Grégoire, X. Montero, M.C. Galetz, G. Bonnet, F. Pedraza

Corrosion Science 216 (2023), 111092, DOI: 10.1016/j.corsci.2023.111092

gregoire2023a

Light optical cross-section micrographs showing the progressive growth of a protrusion on high-purity nickel coated with the simple aluminide coating after exposure to synthetic air + 0.5% SO2/SO3 at 700 °C for 300 h.
Reprinted from Corrosion Science, Copyright (2023), with permission from Elsevier.

A water-based slurry aluminide coating was elaborated on high-purity nickel and tested in synthetic air, synthetic air + 0.5 % SO2/SO3 and synthetic air + 0.5 % SO2/SO3 with sodium sulphate (Na2SO4) deposit at 700 °C. The developed coating considerably increased the oxidation-sulphidation resistance of nickel in the absence of salt through the formation of thin and adherent alumina scales. In contrast, the presence of sodium sulphate decreased the corrosion resistance. Microstructural investigations indicated that aluminium depletion and the related formation of Ni-rich oxides is mainly responsible for the onset of the corrosion attack following sulphation reaction and fluxing mechanisms.

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