Synthesis of Highly Active and Stable Carbon by a Soft-Template Hydrothermal Route as Pt Substrate for Oxygen Reduction Reaction

ChemCatChem (2023) 15, e202201556 https://doi.org/10.1002/cctc.202201556

GRA2KAT Projekt

Abstract

N-doped mesoporous carbon spheres were synthesized by a microwave-assisted ammonia-catalyzed hydrothermal route (C_FAHM) by using Pluronic® F127 as a soft-template and m-Aminophenol as both carbon and nitrogen source. Their physical and electrochemical properties were compared with those of carbon samples obtained by a conventional hydrothermal method (C_FAH). The best results in terms of particle size, surface area, pore size distribution, conductivity and N-content of the as-prepared C_FAHM samples were obtained in 17 M NH₄OH at 120 °C for 5 min. After 1100 °C pyrolysis step, conductivity of C_FAHM increased to 5.64 S cm⁻¹ compared to 8.64 S cm⁻¹ for C_FAH sample. Remarkably, GDE experiments with xylene-swelled C_FAHM-supported platinum exhibited an excellent activity for ORR (181 mA cm⁻² @ 0.7 V) and ECSA retention (80 % after 10,000 ADT) under half-cell conditions in 1 M H₂SO₄ at room temperature compared to only 57 mA cm⁻² and 13 % for GDE with Pt/C_Vulcan reference material.