GZ 205 (101/5)
|Laufzeit:||01.01.2004 - 31.12.2006|
|Partner:||Tianjin University, Prof. Yuxin Wang, China|
|Geldgeber:||Deutsche Forschungsgemeinschaft (DFG)|
|Bearbeiter:||Dr. Jean-Francois Drillet, Prof. Dr, Roland Dittmeyer, Prof. Dr. K. Jüttner|
|Arbeitsgruppe:||Technische Chemie, Elektrochemie|
The direct methanol fuel cell (DMFC) as electrochemical power source has attracted attention due to its simple system design, low operating temperature, and convenient fuel storage and supply. Major limitations of the DMFC are related to the low power density, which is a consequence of the poor kinetics of the anode reaction, poisoning of the catalyst by reaction intermediates, and methanol crossover. Research efforts have to address improvements of the anode catalyst structure and the ion-exchanger membrane.
This project aims at the development of a new type of membrane anode assembly PEM*/PEDOT/CAT based on the conducting polymer PEDOT (Poly(3,4–ethylene-dioxythiophene)) as catalyst support and a new type of proton-exchange membrane (PEM*) with reduced methanol permeability. As the catalyst (CAT) Pt and Pt-Ru will be utilised. The new proton exchange membranes are to be made of thermal-stable polymers of arylide, so that they can be used in fuel cells working at higher temperatures (Tianjin University, China). Conventional Pt/C cathodes will be used for manufacturing the membrane electrode assemblies (MEAs) to be tested in single cell experiments.
The application of PEDOT as mixed electronic and ionic conductor is expected to improve the charge transfer kinetics and the transport of protons and electrons within the anode structure leading to a better utilisation of the noble metal catalyst.
Dr.-Ing. Jean-François Drillet
Tel.: 069 / 75 64-476
J.-F. Drillet, R. Dittmeyer, K. Jüttner, J. Appl. Electrochem., 37 (2007), 1219-1226,
J.-F. Drillet ... K.-M.Mangold, Fuel Cells, 6 (2006), 432-438
L. Li ... K. Jüttner. Russian Journal of Electrochemistry, 42 (2006), 1193-1201
L. Li ... K. Jüttner, J. Solid State Electrochemistry, 10 (2006), 708-713